Macroscopic conductivity of aqueous electrolyte solutions scales with ultrafast microscopic ion motions

Nanometer-scale ion aggregates in aqueous electrolyte solutions: guanidinium carbonate.

Neutron diffraction with isotopic substitution (NDIS) experiments and molecular dynamics (MD) simulations have been used to characterize the structure of aqueous guanidinium carbonate (Gdm2CO3) solutions. The MD simulations found very strong hetero-ion pairing in Gdm2CO3 solution and were used to determine the best structural experiment to demonstrate this ion pairing. The NDIS experiments conf...

Multicomponent Concentrated Aqueous Electrolyte Solutions

Experiment 4: Conductivity of electrolyte solutions

Pure water does not conduct electricity, but any solvated ionic species would contribute to conduction of electricity. An ionically conducting solution is called an electrolyte solution and the compound, which produces the ions as it dissolves, is called an electrolyte. A strong electrolyte is a compound that will completely dissociate into ions in water. Correspondingly, a weak electrolyte dis...

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

Simulation of Pedestrian Dynamics with Macroscopic and Microscopic Mathematical Models

Here, we collect two parts of a research project on the pedestrian flow modeling. Rapid growth in the volume of public transport and the need for its reasonable, efficient planning have made the description and modeling of transport and pedestrian behaviors as important research topics in the past twenty years. First, we present a macroscopic model for the pedestrian flow based on continuum mec...